PEDOT:PSS-free organic solar cells using tetrasulfonic copper phthalocyanine as buffer layer
Identifieur interne : 001729 ( Main/Repository ); précédent : 001728; suivant : 001730PEDOT:PSS-free organic solar cells using tetrasulfonic copper phthalocyanine as buffer layer
Auteurs : RBID : Pascal:12-0090080Descripteurs français
- Pascal (Inist)
- Cellule solaire organique, Couche tampon, Multicouche, Hétérojonction, Couche ITO, Addition étain, Donneur électron, Dispositif photovoltaïque, Courant court circuit, Tension circuit ouvert, Conversion énergie, Taux conversion, Traitement thermique, Cellule solaire, Styrènesulfonate polymère, Thiophène dérivé polymère, Mélange polymère, Phtalocyanine métallique, Complexe de cuivre, Verre, Oxyde d'indium, Acide butyrique, Ester, Aluminium, Composé du fullerène, ITO.
- Wicri :
English descriptors
- KwdEn :
- Aluminium, Buffer layer, Butyric acid, Conversion rate, Copper complex, Electron donor, Energy conversion, Ester, Fullerene compounds, Glass, Heat treatment, Heterojunction, ITO layers, Indium oxide, Metallophthalocyanine, Multiple layer, Open circuit voltage, Organic solar cells, Photovoltaic cell, Polymer blends, Short circuit currents, Solar cell, Styrenesulfonate polymer, Thiophene derivative polymer, Tin addition.
Abstract
This work aims at designing a new poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT :PSS)-free multilayered system for bulk heterojunction organic solar cells. We propose a multilayer structure of glass/indium tin oxide/tetrasulfonated copper phthalocyanine/poly(3-hexylthiophene):[6,61-C61-butyric acid methyl ester/aluminum (ITO/TS-CuPc/P3HT:[60]PCBM/Al). In this architecture, the TS-CuPc is mainly used as a buffer layer instead of PEDOT:PSS and can also act as an electron-donor material and a hole-extraction layer. Photovoltaic devices with a short-circuit current density of 9.7 mA/cm2, a open-circuit voltage of 0.51 V, and a power conversion efficiency of 1.76% were achieved, without post deposition thermal treatment of the P3HT:[60]PCBM blend layer.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">PEDOT:PSS-free organic solar cells using tetrasulfonic copper phthalocyanine as buffer layer</title><author><name sortKey="Bechara, R" uniqKey="Bechara R">R. Bechara</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Advanced Materials and Structures (AMS-CRP Henri Tudor), 66 rue de Luxembourg</s1><s2>9002 Esch sur Alzette</s2><s3>LUX</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ></inist:fA14><country>Luxembourg (pays)</country><wicri:noRegion>9002 Esch sur Alzette</wicri:noRegion></affiliation></author><author><name sortKey="Petersen, J" uniqKey="Petersen J">J. Petersen</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Advanced Materials and Structures (AMS-CRP Henri Tudor), 66 rue de Luxembourg</s1><s2>9002 Esch sur Alzette</s2><s3>LUX</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ></inist:fA14><country>Luxembourg (pays)</country><wicri:noRegion>9002 Esch sur Alzette</wicri:noRegion></affiliation></author><author><name sortKey="Gernigon, V" uniqKey="Gernigon V">V. Gernigon</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Institut d'Electronique du Solide et des Systemes (InESS-UDS-CNRS UMR 7163), 23 rue du Loess, BP 20</s1><s2>67037 Strasbourg</s2><s3>FRA</s3><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Alsace</region><settlement type="city">Strasbourg</settlement></placeName></affiliation></author><author><name sortKey="Leveque, P" uniqKey="Leveque P">P. Leveque</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Institut d'Electronique du Solide et des Systemes (InESS-UDS-CNRS UMR 7163), 23 rue du Loess, BP 20</s1><s2>67037 Strasbourg</s2><s3>FRA</s3><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Alsace</region><settlement type="city">Strasbourg</settlement></placeName></affiliation></author><author><name sortKey="Heiser, T" uniqKey="Heiser T">T. Heiser</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Institut d'Electronique du Solide et des Systemes (InESS-UDS-CNRS UMR 7163), 23 rue du Loess, BP 20</s1><s2>67037 Strasbourg</s2><s3>FRA</s3><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Alsace</region><settlement type="city">Strasbourg</settlement></placeName></affiliation></author><author><name sortKey="Toniazzo, V" uniqKey="Toniazzo V">V. Toniazzo</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Advanced Materials and Structures (AMS-CRP Henri Tudor), 66 rue de Luxembourg</s1><s2>9002 Esch sur Alzette</s2><s3>LUX</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ></inist:fA14><country>Luxembourg (pays)</country><wicri:noRegion>9002 Esch sur Alzette</wicri:noRegion></affiliation></author><author><name sortKey="Ruch, D" uniqKey="Ruch D">D. Ruch</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Advanced Materials and Structures (AMS-CRP Henri Tudor), 66 rue de Luxembourg</s1><s2>9002 Esch sur Alzette</s2><s3>LUX</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ></inist:fA14><country>Luxembourg (pays)</country><wicri:noRegion>9002 Esch sur Alzette</wicri:noRegion></affiliation></author><author><name sortKey="Michel, M" uniqKey="Michel M">M. Michel</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Advanced Materials and Structures (AMS-CRP Henri Tudor), 66 rue de Luxembourg</s1><s2>9002 Esch sur Alzette</s2><s3>LUX</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ></inist:fA14><country>Luxembourg (pays)</country><wicri:noRegion>9002 Esch sur Alzette</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="inist">12-0090080</idno><date when="2012">2012</date><idno type="stanalyst">PASCAL 12-0090080 INIST</idno><idno type="RBID">Pascal:12-0090080</idno><idno type="wicri:Area/Main/Corpus">002188</idno><idno type="wicri:Area/Main/Repository">001729</idno></publicationStmt><seriesStmt><idno type="ISSN">0927-0248</idno><title level="j" type="abbreviated">Sol. energy mater. sol. cells</title><title level="j" type="main">Solar energy materials and solar cells</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Aluminium</term><term>Buffer layer</term><term>Butyric acid</term><term>Conversion rate</term><term>Copper complex</term><term>Electron donor</term><term>Energy conversion</term><term>Ester</term><term>Fullerene compounds</term><term>Glass</term><term>Heat treatment</term><term>Heterojunction</term><term>ITO layers</term><term>Indium oxide</term><term>Metallophthalocyanine</term><term>Multiple layer</term><term>Open circuit voltage</term><term>Organic solar cells</term><term>Photovoltaic cell</term><term>Polymer blends</term><term>Short circuit currents</term><term>Solar cell</term><term>Styrenesulfonate polymer</term><term>Thiophene derivative polymer</term><term>Tin addition</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Cellule solaire organique</term><term>Couche tampon</term><term>Multicouche</term><term>Hétérojonction</term><term>Couche ITO</term><term>Addition étain</term><term>Donneur électron</term><term>Dispositif photovoltaïque</term><term>Courant court circuit</term><term>Tension circuit ouvert</term><term>Conversion énergie</term><term>Taux conversion</term><term>Traitement thermique</term><term>Cellule solaire</term><term>Styrènesulfonate polymère</term><term>Thiophène dérivé polymère</term><term>Mélange polymère</term><term>Phtalocyanine métallique</term><term>Complexe de cuivre</term><term>Verre</term><term>Oxyde d'indium</term><term>Acide butyrique</term><term>Ester</term><term>Aluminium</term><term>Composé du fullerène</term><term>ITO</term></keywords><keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Verre</term><term>Aluminium</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">This work aims at designing a new poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT :PSS)-<sub>f</sub>ree multilayered system for bulk heterojunction organic solar cells. We propose a multilayer structure of glass/indium tin oxide/tetrasulfonated copper phthalocyanine/poly(3-hexylthiophene):[6,61-C<sub>61</sub>-butyric acid methyl ester/aluminum (ITO/TS-CuPc/P3HT:[60]PCBM/Al). In this architecture, the TS-CuPc is mainly used as a buffer layer instead of PEDOT:PSS and can also act as an electron-donor material and a hole-extraction layer. Photovoltaic devices with a short-circuit current density of 9.7 mA/cm<sup>2</sup>, a open-circuit voltage of 0.51 V, and a power conversion efficiency of 1.76% were achieved, without post deposition thermal treatment of the P3HT:[60]PCBM blend layer.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0927-0248</s0></fA01><fA03 i2="1"><s0>Sol. energy mater. sol. cells</s0></fA03><fA05><s2>98</s2></fA05><fA08 i1="01" i2="1" l="ENG"><s1>PEDOT:PSS-free organic solar cells using tetrasulfonic copper phthalocyanine as buffer layer</s1></fA08><fA11 i1="01" i2="1"><s1>BECHARA (R.)</s1></fA11><fA11 i1="02" i2="1"><s1>PETERSEN (J.)</s1></fA11><fA11 i1="03" i2="1"><s1>GERNIGON (V.)</s1></fA11><fA11 i1="04" i2="1"><s1>LEVEQUE (P.)</s1></fA11><fA11 i1="05" i2="1"><s1>HEISER (T.)</s1></fA11><fA11 i1="06" i2="1"><s1>TONIAZZO (V.)</s1></fA11><fA11 i1="07" i2="1"><s1>RUCH (D.)</s1></fA11><fA11 i1="08" i2="1"><s1>MICHEL (M.)</s1></fA11><fA14 i1="01"><s1>Department of Advanced Materials and Structures (AMS-CRP Henri Tudor), 66 rue de Luxembourg</s1><s2>9002 Esch sur Alzette</s2><s3>LUX</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ></fA14><fA14 i1="02"><s1>Institut d'Electronique du Solide et des Systemes (InESS-UDS-CNRS UMR 7163), 23 rue du Loess, BP 20</s1><s2>67037 Strasbourg</s2><s3>FRA</s3><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></fA14><fA20><s1>482-485</s1></fA20><fA21><s1>2012</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>18016</s2><s5>354000508662100680</s5></fA43><fA44><s0>0000</s0><s1>© 2012 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>17 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>12-0090080</s0></fA47><fA60><s1>P</s1><s3>CR</s3></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Solar energy materials and solar cells</s0></fA64><fA66 i1="01"><s0>NLD</s0></fA66><fC01 i1="01" l="ENG"><s0>This work aims at designing a new poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT :PSS)-<sub>f</sub>ree multilayered system for bulk heterojunction organic solar cells. We propose a multilayer structure of glass/indium tin oxide/tetrasulfonated copper phthalocyanine/poly(3-hexylthiophene):[6,61-C<sub>61</sub>-butyric acid methyl ester/aluminum (ITO/TS-CuPc/P3HT:[60]PCBM/Al). In this architecture, the TS-CuPc is mainly used as a buffer layer instead of PEDOT:PSS and can also act as an electron-donor material and a hole-extraction layer. Photovoltaic devices with a short-circuit current density of 9.7 mA/cm<sup>2</sup>, a open-circuit voltage of 0.51 V, and a power conversion efficiency of 1.76% were achieved, without post deposition thermal treatment of the P3HT:[60]PCBM blend layer.</s0></fC01><fC02 i1="01" i2="X"><s0>001D06C02D1</s0></fC02><fC02 i1="02" i2="X"><s0>001D05I03D</s0></fC02><fC02 i1="03" i2="X"><s0>230</s0></fC02><fC03 i1="01" i2="3" l="FRE"><s0>Cellule solaire organique</s0><s5>01</s5></fC03><fC03 i1="01" i2="3" l="ENG"><s0>Organic solar cells</s0><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Couche tampon</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Buffer layer</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Capa tampón</s0><s5>02</s5></fC03><fC03 i1="03" i2="X" l="FRE"><s0>Multicouche</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="ENG"><s0>Multiple layer</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="SPA"><s0>Capa múltiple</s0><s5>03</s5></fC03><fC03 i1="04" i2="X" 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